Melting point of strontium. Chemical element strontium - description, properties and formula

STRONTIUM (Strontium, Sr) - a chemical element of the periodic system of D. I. Mendeleev, a subgroup of alkaline earth metals. In the human body, S. competes with calcium (see) for inclusion in the crystal lattice of bone oxyapatite (see). 90 Sr, one of the longest-lived radioactive fission products of uranium (see), accumulating in the atmosphere and biosphere during testing nuclear weapons(see), represents a great danger to humanity. S.'s radioactive isotopes are used in medicine for radiation therapy (see), as a radioactive label in diagnostic radiopharmaceuticals (see) in medical biol. research, as well as in atomic electric batteries. S. compounds are used in flaw detectors, in sensitive instruments, in devices for combating static electricity, in addition, S. is used in radio electronics, pyrotechnics, metallurgical, chemical industry and in the manufacture ceramic products. S.'s connections are not poisonous. When working with metal S., one should be guided by the rules for handling alkali metals (see) and alkaline earth metals (see).

S. was discovered in the composition of the mineral, later called SrC03 strontianite, in 1787 near the Scottish city of Strontiana.

The serial number of strontium is 38, atomic weight(mass) 87.62. The content of S. in the earth's crust averages 4-10 2 wt. %, in sea water - 0.013% (13 mg / l). The minerals strontianite and celestite SrSO 4 are of industrial importance.

The human body contains approx. 0.32 g of strontium, mainly in bone tissue, in the blood, the concentration of S. is normally 0.035 mg / l, in the urine - 0.039 mg / l.

S. is a soft silvery-white metal, t°pl 770°, t°kip 1383°.

According to chem. S.'s properties are similar to calcium and barium (see), in compounds the valence of strontium is 4-2, it is chemically active, it is oxidized at normal conditions water with the formation of Sr (OH) 2, as well as oxygen and other oxidizing agents.

S. enters the human body hl. arr. with plant foods, as well as with milk. It is absorbed in the small intestine and quickly exchanges with S. contained in the bones. S.'s removal from an organism is strengthened by complexes, amino acids, polyphosphates. The increased content of calcium and fluorine (see) in water interferes with S.'s cumulation in bones. With an increase in the concentration of calcium in the diet by 5 times, S.'s accumulation in the body is halved. Excessive S.'s intake with food and water due to its increased content in the soil of some geochemical. provinces (for example, in separate districts Eastern Siberia) causes an endemic disease - Urov's disease (see Kashin-Beck disease).

In bones, blood and other biol. S.'s substrates define hl. arr. spectral methods (see Spectroscopy).

radioactive strontium

Natural S. consists of four stable isotopes with mass numbers 84, 86, 87, and 88, of which the latter is the most common (82.56%). Eighteen radioactive isotopes of sulfur are known (with mass numbers 78–83, 85, 89–99) and four isomers of isotopes with mass numbers 79, 83, 85, and 87 (see Isomerism).

In medicine, 90Sr is used for radiation therapy in ophthalmology and dermatology, as well as in radiobiological experiments as a source of β-radiation. 85Sr is produced either by irradiating a strontium target enriched in the 84Sr isotope with neutrons in a nuclear reactor by the reaction 84Sr (11.7) 85Sr, or produced at a cyclotron by irradiating natural rubidium targets with protons or deuterons, for example, by the reaction 85Rb (p, n) 85Sr. The radionuclide 85Sr decays with electron capture, emitting gamma radiation with an energy E gamma equal to 0.513 MeV (99.28%) and 0.868 MeV (< 0,1%).

87mSr can also be obtained by irradiating a strontium target in a reactor by the reaction 86Sr (n, gamma) 87mSr, but the yield of the desired isotope is low, in addition, 85Sr and 89Sr isotopes are formed simultaneously with 87mSr. Therefore, usually 87niSr is obtained using an isotope generator (see Radioactive Isotope Generators) based on the parent isotope of yttrium-87 - 87Y (T1 / 2 = 3.3 days). 87mSr decays with an isomeric transition, emitting gamma radiation with an Egamma energy of 0.388 MeV, and partly with electron capture (0.6%).

89Sr is contained in fission products together with 90Sr; therefore, 89Sr is obtained by irradiating natural sulfur in a reactor. In this case, an 85Sr impurity is also inevitably formed. The 89Sr isotope decays with the emission of P-radiation with an energy of 1.463 MeV (approx. 100%). The spectrum also contains a very weak line of gamma radiation with an energy E gamma equal to 0.95 MeV (0.01%).

90Sr is obtained by isolation from a mixture of uranium fission products (see). This isotope decays with the emission of beta radiation with an energy of E beta equal to 0.546 Meu (100%), without accompanying gamma radiation. The decay of 90Sr leads to the formation of a daughter radionuclide 90Y, which decays (T1 / 2 = 64 hours) with the emission of p-radiation, consisting of two components with Ep equal to 2.27 MeV (99%) and 0.513 MeV (0 .02%). The decay of 90Y also emits very weak gamma radiation with an energy of 1.75 MeV (0.02%).

Radioactive isotopes 89Sr and 90Sr, which are present in the waste of the nuclear industry and are formed during nuclear weapons testing, can enter the human body with food, water, and air when the environment is polluted. Quantification of S.'s migration in the biosphere is usually carried out in comparison with calcium. In most cases, when 90Sr moves from the previous link in the chain to the next, the concentration of 90Sr decreases per 1 g of calcium (the so-called discrimination coefficient), in adults in the body-diet link, this coefficient is 0.25.

Like soluble compounds of other alkaline earth elements, soluble compounds of S. are well absorbed from went. - kish. a path (10-60%), absorption of poorly soluble connections S. (eg, SrTi03) makes less than 1%. The degree of absorption of S.'s radionuclides in the intestine depends on age. With an increase in the calcium content in the diet, S.'s accumulation in the body decreases. Milk promotes increase in S.'s absorption and calcium in intestines. It is believed that this is due to the presence of lactose and lysine in milk.

When inhaled, soluble S. compounds are quickly eliminated from the lungs, while poorly soluble SrTi03 is exchanged in the lungs extremely slowly. Penetration of radionuclide S. through the intact skin makes apprx. one%. Through damaged skin (cut wound, burns, etc.)? as well as from subcutaneous tissue and muscle tissue, S. is absorbed almost completely.

S. is an osteotropic element. Regardless of the route and rhythm of entry into the body, soluble 90Sr compounds selectively accumulate in the bones. AT soft tissues less than 1% 90Sr is retained.

With intravenous administration, S. is very quickly eliminated from the bloodstream. Soon after administration, the concentration of S. in the bones becomes 100 times or more higher than in soft tissues. Nek-ry distinctions in accumulation 90Sr in separate bodies and fabrics are noted. A relatively higher concentration of 90Sr in experimental animals is found in the kidneys, salivary and thyroid glands, and the lowest concentration is found in the skin, bone marrow and adrenal glands. The concentration of 90Sr in the renal cortex is always higher than in the medulla. S. initially lingers on the bone surfaces (periosteum, endosteum), and then is distributed relatively evenly throughout the entire volume of the bone. Nevertheless, the distribution of 90Sr in different parts of the same bone and in different bones turns out to be uneven. During the first time after injection, the concentration of 90Sr in the epiphysis and metaphysis of the bone of experimental animals is approximately 2 times higher than in the diaphysis. From the epiphysis and metaphysis, 90Sr is excreted faster than from the diaphysis: in 2 months. the concentration of 90Sr in the epiphysis and metaphysis of the bone decreases by 4 times, and in the diaphysis almost does not change. Initially 90Sr concentrates in those sites in which there is an active formation of a bone. Abundant blood and lymph circulation in the epimetaphyseal areas of the bone contributes to a more intense deposition of 90Sr in them compared to the diaphysis of the tubular bone. The amount of 90Sr deposition in the bones of animals is not constant. A sharp decrease in 90Sr fixation in bones with age was found in all animal species. Deposition of 90Sr in the skeleton significantly depends on gender, pregnancy, lactation, and the state of the neuroendocrine system. A higher deposition of 90Sr in the skeleton was noted in male rats. In the skeleton of pregnant females, 90Sr accumulates less (up to 25%) than in control animals. Lactation has a significant effect on the accumulation of 90Sr in the skeleton of females. With the introduction of 90Sr 24 hours after birth, 90Sr is retained in the skeleton of rats 1.5-2 times less than in non-lactating females.

The penetration of 90Sr into the tissues of the embryo and fetus depends on the stage of their development, the state of the placenta, and the duration of circulation of the isotope in the mother's blood. Penetration of 90Sr into the fetus is the greater, the longer the gestational age at the time of administration of the radionuclide.

To reduce the damaging effect of strontium radionuclides, it is necessary to limit their accumulation in the body. For this purpose, when the skin is contaminated, it is necessary to quickly decontaminate its open areas (Protection-7 preparation, Era or Astra washing powders, NEDE paste). In case of oral intake of strontium radionuclides, antidotes should be used to bind or absorb the radionuclide. Such antidotes include activated barium sulfate (adso-bar), polysurmin, alginic acid preparations, etc. For example, the drug adsobar, when taken immediately after radionuclides enter the stomach, reduces their absorption by 10-30 times. Adsorbents and antidotes should be prescribed immediately after detection of damage by strontium radionuclides, since delay in this case leads to sharp decline their positive action. At the same time, it is recommended to prescribe emetics (apomorphine) or to produce abundant gastric lavage, use saline laxatives, cleansing enemas. In case of damage by dust-like preparations, abundant washing of the nose and oral cavity, expectorants (thermopsis with soda), ammonium chloride, injections of calcium preparations, diuretics are necessary. In more late dates after the defeat, to reduce the deposition of radionuclides S. in the bones, it is recommended to use the so-called. stable strontium (S. lactate or S. gluconate). Large doses of oral calcium or intravenous MofyT replace stable strontium preparations if these are not available. In connection with the good reabsorption of strontium radionuclides in the renal tubules, the use of diuretics is also indicated.

Nek-swarm decrease in accumulation of S.'s radionuclides in an organism can be reached by creation of competitive relations between them and stable isotope S. or calcium, and also creation of deficiency of these elements when S.'s radionuclide was already fixed in a skeleton. However effective means decorporation of radioactive strontium from the body has not yet been found.

The minimum significant activity that does not require registration or permission from the State Sanitary Inspection for 85mSr, 85Sr, 89Sr and 90Sr is 3.5*10 -8 , 10 -10 , 2.8*10 -11 and 1.2*10, respectively -12 curies/l.

Bibliography: Borisov V.P. and others. Urgent care with acute radiation exposure, M., 1976; Buldakov L. A. and Moskalev Yu. I. Problems of distribution and experimental estimation acceptable levels Cs137, Sr90 and Ru106, M., 1968, bibliogr.; Voinar A. I. The biological role of trace elements in the body of animals and humans, p. 46, M., 1960; Ilyin JI. A. and Ivannikov A. T. Radioactive substances and wounds, M., 1979; To and with and in fi-on B. S. and T about r ben to about V. P. Life of a bone tissue, M., 1979; JI e in and V. I N. Obtaining radioactive preparations, M., 1972; Metabolism of strontium, ed. J. M. A. Lenihena and others, trans. from English, M., 1971; Poluektov N. S. and others. Analytical chemistry of strontium, M., 1978; P e m and G. The course is not organic chemistry, per. from German, vol. 1, M., 1972; Protection of the patient in radionuclide investigations, Oxford, 1969, bibliogr.; Table of isotopes, ed. by C. M. Lederer a. V. S. Shirley, N. Y. a. o., 1978.

A. V. Babkov, Yu. I. Moskalev (rad.).

Strontium

atomic number
Appearance a simple substance
malleable, silvery-white metal
Atom properties
Atomic mass
(molar mass)

87.62 a. e.m. (g/mol)

Atom radius
Ionization energy
(first electron)

549.0 (5.69) kJ/mol (eV)

Electronic configuration
Chemical properties
covalent radius
Ion radius
Electronegativity
(according to Pauling)
Electrode potential
Oxidation states
Thermodynamic properties of a simple substance
Density
Molar heat capacity

26.79 J/(K mol)

Thermal conductivity

(35.4) W/(m K)

Melting temperature
Melting heat

9.20 kJ/mol

Boiling temperature
Heat of evaporation

144 kJ/mol

Molar volume

33.7 cm³/mol

The crystal lattice of a simple substance
Lattice structure

cubic face-centered

Lattice parameters
c/a ratio
Debye temperature
Sr 38
87,62
5s 2
Strontium

Strontium- an element of the main subgroup of the second group, the fifth period of the periodic system of chemical elements of D. I. Mendeleev, with atomic number 38. It is denoted by the symbol Sr (lat. Strontium). The simple substance strontium (CAS number: 7440-24-6) is a soft, malleable and ductile silver-white alkaline earth metal. It has a high chemical activity, in air it quickly reacts with moisture and oxygen, becoming covered with a yellow oxide film.

History and origin of the name

The new element was discovered in the mineral strontianite, found in 1764 in a lead mine near the Scottish village of Stronshian, which later gave the name to the new element. The presence of a new metal oxide in this mineral was established almost 30 years later by William Cruikshank and Ader Crawford. Isolated in its purest form by Sir Humphry Davy in 1808.

Presence in nature

Strontium is found in sea water (0.1 mg/l), in soils (0.035 wt %).

In nature, strontium occurs as a mixture of 4 stable isotopes 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.02%), 88Sr (82.56%).

Obtaining Strontium

Three ways to obtain metallic strontium:

- thermal decomposition of some compounds
– electrolysis
- reduction of oxide or chloride

The main industrial method for obtaining metallic strontium is the thermal reduction of its oxide with aluminum. Further, the resulting strontium is purified by sublimation.

The electrolytic production of strontium by electrolysis of a melt of a mixture of SrCl 2 and NaCl has not become widespread due to the low current efficiency and contamination of strontium with impurities.

During thermal decomposition of strontium hydride or nitride, finely dispersed strontium is formed, which is prone to easy ignition.

Physical properties

Strontium is a soft, silvery-white metal, malleable and malleable, and can be easily cut with a knife.

Polymorphine - three of its modifications are known. Up to 215 o C, the cubic face-centered modification (α-Sr) is stable, between 215 and 605 o C - hexagonal (β-Sr), above 605 o C - cubic body-centered modification (γ-Sr).

Melting point - 768 o C, Boiling point - 1390 o C.

Chemical properties

Strontium in its compounds always exhibits a +2 valency. By properties, strontium is close to calcium and barium, occupying an intermediate position between them.

In the electrochemical series of voltages, strontium is among the most active metals (its normal electrode potential is −2.89 V. It reacts vigorously with water, forming hydroxide:

Sr + 2H 2 O \u003d Sr (OH) 2 + H 2

Reacts with acids heavy metals from their salts. With concentrated acids (H 2 SO 4 , HNO 3) reacts weakly.

Strontium metal rapidly oxidizes in air, forming a yellowish film, in which, in addition to SrO oxide, SrO 2 peroxide and Sr 3 N 2 nitride are always present. When heated in air, it ignites; powdered strontium in air is prone to self-ignition.

Vigorously reacts with non-metals - sulfur, phosphorus, halogens. Interacts with hydrogen (above 200 o C), nitrogen (above 400 o C). Practically does not react with alkalis.

At high temperatures, it reacts with CO 2, forming a carbide:

5Sr + 2CO 2 = SrC 2 + 4SrO

Easily soluble salts of strontium with anions Cl - , I - , NO 3 - . Salts with anions F -, SO 4 2-, CO 3 2-, PO 4 3- are sparingly soluble.

Application

The main areas of application of strontium and its chemical compounds are the radio-electronic industry, pyrotechnics, metallurgy, and the food industry.

Metallurgy

Strontium is used for alloying copper and some of its alloys, for introducing into battery lead alloys, for desulfurizing cast iron, copper and steels.

Metalthermy

Strontium with a purity of 99.99-99.999% is used to reduce uranium.

Magnetic materials

Magnetically hard strontium ferrites are widely used materials for the production of permanent magnets.

Pyrotechnics

In pyrotechnics, strontium carbonate, nitrate, perchlorate are used to color the flame in a brick red color. The magnesium-strontium alloy has the strongest pyrophoric properties and is used in pyrotechnics for incendiary and signal compositions.

isotopes

Radioactive 90 Sr (half-life 28.9 years) is used in the production of radioisotope power sources in the form of strontium titanate (density 4.8 g/cm³, energy release about 0.54 W/cm³).

Nuclear energy

Strontium uranate plays an important role in the production of hydrogen (strontium-uranate cycle, Los Alamos, USA) by the thermochemical method (atomic hydrogen energy), and in particular, methods are being developed for the direct fission of uranium nuclei in the composition of strontium uranate to produce heat during the decomposition of water into hydrogen and oxygen.

High temperature superconductivity

Strontium oxide is used as a component of superconducting ceramics.

Chemical current sources

Strontium fluoride is used as a component of solid-state fluorine batteries with enormous energy capacity and energy density.

Alloys of strontium with tin and lead are used for casting battery down conductors. Strontium-cadmium alloys for anodes of galvanic cells.

Biological role

Impact on the human body

One should not confuse the effect on the human body of natural (non-radioactive, low-toxic, and moreover, widely used for the treatment of osteoporosis) and radioactive isotopes of strontium. The strontium isotope 90 Sr is radioactive with a half-life of 28.9 years. 90 Sr undergoes β-decay, turning into radioactive 90 Y (half-life 64 hours). The complete decay of strontium-90 that has entered the environment will occur only after several hundred years. 90 Sr is formed during nuclear explosions and emissions from nuclear power plants. Radioactive and non-radioactive isotopes of strontium practically do not differ in chemical reactions. Strontium natural - component microorganisms, plants and animals. Regardless of the route and rhythm of entry into the body, soluble strontium compounds accumulate in the skeleton. Less than 1% is retained in soft tissues. The route of entry affects the amount of strontium deposition in the skeleton. The behavior of strontium in the body is influenced by the type, gender, age, as well as pregnancy, and other factors. For example, in the skeleton of men, deposits are higher than in the skeleton of women. Strontium is an analogue of calcium. Strontium accumulates at a high rate in the body of children up to the age of four, when there is an active formation of bone tissue. The exchange of strontium changes in some diseases of the digestive system and the cardiovascular system. Entry routes:

  1. water (the maximum permissible concentration of strontium in water in the Russian Federation is 8 mg / l, and in the USA - 4 mg / l)
  2. food (tomatoes, beets, dill, parsley, radish, radish, onion, cabbage, barley, rye, wheat)
  3. intratracheal intake
  4. through the skin (cutaneous)
  5. inhalation (through the air)
  6. from plants or through animals, strontium-90 can directly pass into the human body.
  7. people whose work is related to strontium (in medicine, radioactive strontium is used as applicators in the treatment of skin and eye diseases. The main areas of application of natural strontium are the radio-electronic industry, pyrotechnics, metallurgy, metallothermy, food industry, production of magnetic materials, radioactive - pr - in atomic electric batteries, atomic hydrogen energy, radioisotope thermoelectric generators, etc.)

The influence of non-radioactive strontium is extremely rare and only under the influence of other factors (deficiency of calcium and vitamin D, malnutrition, violations of the ratio of trace elements such as barium, molybdenum, selenium, etc.). Then it can cause "strontium rickets" and "ur disease" in children - joint damage and deformity, growth retardation and other disorders. On the contrary, radioactive strontium almost always negatively affects the human body:

  1. deposited in the skeleton (bones), affects the bone tissue and bone marrow, which leads to the development of radiation sickness, tumors of the hematopoietic tissue and bones.
  2. causes leukemia and malignant tumors(cancer) of the bones, as well as damage to the liver and brain

isotopes

Strontium-90

The strontium isotope 90 Sr is radioactive with a half-life of 28.79 years. 90 Sr undergoes β-decay, turning into radioactive yttrium 90 Y (half-life 64 hours). 90 Sr is formed during nuclear explosions and emissions from nuclear power plants.

Strontium is an analogue of calcium and is able to be firmly deposited in the bones. long radiation exposure 90 Sr and 90 Y affects bone tissue and bone marrow, which leads to the development of radiation sickness, tumors of the hematopoietic tissue and bones.

Its name comes from the village of Strontian in Scotland, where the mineral containing strontium was discovered. In 1790, strontium was identified as an individual element by A. Crawford and W. Cruikshank. G. Davy first isolated metallic strontium in 1808.

Receipt:

Strontium accounts for 0.008% total number atoms earth's crust. In addition to silicate rocks, strontium occurs in the form of its sparingly soluble carbonic and sulphate salts: SrCO 3 - strontianite, SrSO 4 - celestine.
In the free state, it can be obtained by heating the oxide with metallic aluminum in high vacuum:
3SrO+2Al=Al 2 O 3 +3Sr

Physical properties:

Like calcium, strontium is a malleable golden yellow metal and is much softer than calcium. Volatile compounds of strontium color the flame carmine red.

Chemical properties:

In air, strontium is covered with a film containing, along with oxide, peroxide and strontium nitride. Due to rapid oxidation, the metal is stored in mineral oil or sealed in ampoules.
Reacts when heated with hydrogen and nitrogen, halogens. Easily displaces hydrogen not only from dilute acids, but also from water. Soluble in liquid ammonia. It is divalent in its compounds.

The most important connections:

Strontium oxide is a white refractory substance that vigorously attaches water to form a white hydroxide. Along with the oxide, white strontium(II) peroxide is known
Strontium hydroxide, Sr(OH) 2- strong base, highly soluble in water. When interacting with acids, the oxide and hydroxide easily form salts, usually colorless.
Strontium nitrate, Sr(NO 3) 2 is allocated in the form of crystalline hydrates, which are very easily soluble in water. Nitrates are similar in composition to chlorates, bromates, and iodates.
The solubility of salts in water decreases in the series: Ca - Sr - Ba and Cl - Br - I.
Strontium sulfide is a white solid. Strontium polysulfides SrS n are known.

Application:

Strontium is a getter in electrovacuum devices, a modifier of alloys, cast irons and steels. Radioactive isotopes 89 Sr and 90 Sr are used as sources b-radiation.
Strontium nitrate is used in pyrotechnics for the manufacture of compositions that, when burned, give a brightly colored red flame (fireworks and flares).
Many strontium compounds are used as components of ceramics, phosphors, and optical materials.
Strontium is able to accumulate in the human body, replacing calcium, which leads to increased bone fragility. But if this is not natural strontium, but resulting from nuclear explosions 90 Sr, the consequences are much more severe: bone marrow damage, leukemia, radiation sickness.

Elmik Galina

See also:
S.I. Venetsky. About the rare and scattered. Metal stories.

Strontium- alkaline earth metal. It is a substance of a silvery-white color (see photo), very soft and plastic, easily cut even with an ordinary knife. Possesses high activity, burns in the presence of air, enters into chemical interactions with water. AT natural conditions not found in pure form. It is mainly found in the composition of fossil minerals, usually in combination with calcium.

It was first found in Scotland at the end of the 18th century in a village with the name Stronshian, which gave the name to the found mineral - strontianite. But only 30 years after the discovery, the English scientist H. Davy was able to isolate it in its pure form.

Element compounds are used in metallurgical production, medicine, Food Industry. Very interesting is its property, when burning, to emit fires of a red hue, which were adopted by pyrotechnics at the beginning of the 20th century.

The action of strontium and its biological role

Many associate the action of a macroelement with high toxicity and radioactivity. But such an opinion is rather erroneous, because. the natural element practically does not possess these qualities and is even present in tissues biological organisms, performing an important biological role and some functions as a satellite of calcium. Due to the properties of the substance, it is used for medical purposes.

The main accumulation of strontium in the human body falls on bone tissue. This is due to the fact that the element is similar to calcium in chemical action, and calcium, in turn, is the main component of the "construction" of the skeleton. But the muscles contain only 1% of the total mass of the element in the body.

Strontium is also present in the deposits of bile and urinary stones again in the presence of calcium.

By the way, about the harmfulness of strontium - only radioactive isotopes have a devastating effect on health, who in their own way chemical properties practically indistinguishable from the natural element. Perhaps this is the reason for this confusion.

Daily rate

The daily norm of a macronutrient is approximately 1 mg. This amount is quite easily replenished with food and drinking water. In total, approximately 320 mg of strontium is distributed in the body.

But it should be borne in mind that our body is able to absorb only 10% of the incoming element, and we get up to 5 mg per day.

Strontium deficiency

The lack of a macronutrient can only theoretically cause some pathologies, but so far this has been shown only in animal experiments. So far, scientists have not identified negative impact strontium deficiency on the human body.

At the moment, only some dependences of the assimilation of this macronutrient under the influence of other substances in the body have been identified. For example, this process is facilitated by certain amino acids, the intake of vitamins D and lactose. And drugs based on barium or sodium sulfates, as well as products with a high content of dietary coarse fibers, have an opposite effect.

There is another unpleasant feature - when calcium deficiency occurs, the body begins to accumulate radioactive strontium even from the air (often polluted by industrial enterprises).

Why is strontium dangerous for humans and what is its harm?

Strontium, after all, is capable of exerting a harmful radioactive effect. The element itself does little harm, and a critical dose has not yet been established. But its isotopes can cause diseases and various disorders. Like natural strontium, it accumulates in the skeleton itself, but its action causes damage to the bone marrow and destruction of the very structure of the bones. It can affect the cells of the brain and liver, and thus cause the occurrence of neoplasms and tumors.

But one of the most terrible consequences of exposure to the isotope is radiation sickness. The consequences of the Chernobyl disaster are still being felt in our country, and the accumulated reserves of radioactive strontium make themselves felt in the soil, water and the atmosphere itself. You can also get a large dose by working at enterprises using the element - there high level bone sarcoma and leukemia.

But natural strontium can also cause unpleasant consequences. Due to a rather rare set of circumstances such as an inadequate diet, a lack of calcium, vitamin D, and an imbalance in the body of elements such as selenium and molybdenum, specific diseases develop - strontium rickets and uric disease. The latter got its name from the area where local residents suffered from them back in the 19th century. They became disabled due to the curvature of the structure of the skeleton, bones and joints. Moreover, for the most part, those people who grew up in these places from childhood suffered. Only in the 20th century did they find out that the waters of the local river contained an increased amount of the element. And during the period of growth, it is the musculoskeletal system that is most affected.

Contact with strontium oxide on the mucous membranes of the mouth or eyes can cause burns and deep damage. And inhaling it with air can contribute to the development of pathological diseases in the lungs - fibrosis, bronchitis, and heart failure is also possible.

As treatment, drugs based on calcium, magnesium, sodium sulfate or barium are usually used. It is also possible to use complexing agents that bind and remove radioactive toxins from cells.

Getting into the soil, the toxic isotope of strontium is thus able to accumulate in plant fibers, and then in animal organisms. In this way human body slowly but surely accumulates toxins by eating poisoned foods. Heat treatment of products can save the situation a little, which contributes to a fairly significant reduction in the content of harmful toxin in them.

This radionuclide is very difficult to remove from the body, because it may take him almost half a year to get rid of at least half of the accumulated stock.

What food contains?

Indications for treatment with drugs based on this element

There are still indications for the appointment of a macroelement, despite its possible toxicity. And even a radioactive isotope is used for medical purposes. Its radiation in allowed doses can have a therapeutic effect on erosions, tumors on the skin and mucous membranes. With deeper foci, this method is already used.

Also, its compounds serve as drugs for the treatment of epilepsy, nephritis and correction of deformity in childhood by orthopedists. To some extent, it can serve as an antihelminthic agent.

Strontium- an element of the main subgroup of the second group, the fifth period of the periodic system of chemical elements of D. I. Mendeleev, with atomic number 38. It is denoted by the symbol Sr (lat. Strontium). The simple substance strontium is a soft, malleable and ductile alkaline earth metal of a silvery-white color. It has a high chemical activity, in air it quickly reacts with moisture and oxygen, becoming covered with a yellow oxide film.

38 Strontium→ Yttrium
Atom properties
Name, symbol, number

Strontium / Strontium (Sr), 38

Atomic mass
(molar mass)

87.62(1) a. e.m. (g/mol)

Electronic configuration
Atom radius
Chemical properties
covalent radius
Ion radius
Electronegativity

0.95 (Pauling scale)

Electrode potential
Oxidation states
Ionization energy
(first electron)

549.0 (5.69) kJ/mol (eV)

Thermodynamic properties of a simple substance
Density (at n.a.)
Melting temperature
Boiling temperature
Oud. heat of fusion

9.20 kJ/mol

Oud. heat of evaporation

144 kJ/mol

Molar heat capacity

26.79 J/(K mol)

Molar volume

33.7 cm³/mol

The crystal lattice of a simple substance
Lattice structure

cubic face-centered

Lattice parameters
Debye temperature
Other characteristics
Thermal conductivity

(300 K) (35.4) W/(m K)

In 1764, a mineral was found in a lead mine near the Scottish village of Strontian, which they called strontianite. For a long time it was considered a variety of fluorite CaF2 or witherite BaCO3, but in 1790 the English mineralogists Crawford and Cruikshank analyzed this mineral and found that it contained a new "earth", and in today's language, oxide.

Independently of them, the same mineral was studied by another English chemist, Hope. Having come to the same results, he announced that there is a new element in strontianite - the metal strontium.

Apparently, the discovery was already "in the air", because almost simultaneously the prominent German chemist Klaproth announced the discovery of a new "earth".

In the same years, the well-known Russian chemist, academician Toviy Egorovich Lovitz, also came across traces of "strontium earth". He had long been interested in the mineral known as heavy spar. In this mineral (its composition is BaSO4), Karl Scheele discovered in 1774 the oxide of the new element barium. We do not know why Lovitz was not indifferent to heavy spar; it is only known that the scientist, who discovered the adsorption properties of coal and did much more in the field of general and organic chemistry, collected samples of this mineral. But Lovitz was not just a collector, he soon began to systematically study heavy spar and in 1792 came to the conclusion that this mineral contained an unknown impurity. He managed to extract quite a lot from his collection - more than 100 g of new "earth" and continued to explore its properties. The results of the study were published in 1795.

So, almost simultaneously, several researchers in different countries came close to the discovery of strontium. But in its elementary form it was singled out only in 1808.

The outstanding scientist of his time, Humphry Davy, already understood that the element of strontium earth must, apparently, be an alkaline earth metal, and he obtained it by electrolysis, i.e. in the same way as calcium, magnesium, barium. More specifically, the world's first metallic strontium was obtained by electrolysis of its moistened hydroxide. The strontium released at the cathode instantly combined with mercury, forming an amalgam. Decomposing the amalgam by heating, Davy isolated the pure metal.